Logarithmic oscillator thermostat
The Logarithmic oscillator [1] in one dimension is given by (Eq. 2):
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle H = \frac{P^2}{2M}+ T \ln \frac{\vert X \vert}{b}}
where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle X} is the position of the logarithmic oscillator, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle P} is its linear momentum, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle M} represents its mass. Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T} is the desired temperature of the thermostat, and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle b > 0} sets a length-scale.
As a thermostat
From the Virial theorem
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \left\langle X\frac{\partial H}{\partial X} \right\rangle = \left\langle P\frac{\partial H}{\partial P} \right\rangle }
one obtains
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T = \left\langle \frac{P^2}{M} \right\rangle } .
This implies that all expectation values of the trajectories correspond to the very same temperature of the thermostat, irrespective of the internal energy. In other words,
this implies that the heat capacity becomes
- Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle C_V := \left. \frac{\partial U}{\partial T} \right\vert_V = \infty }
Having an infinite heat capacity is an ideal feature for a thermostat.
Practical applicability
References
- ↑ Michele Campisi, Fei Zhan, Peter Talkner, and Peter Hänggi "Logarithmic Oscillators: Ideal Hamiltonian Thermostats", Physical Review Letters 108 250601 (2012)
- ↑ Marc Meléndez Schofield "On the logarithmic oscillator as a thermostat", arXiv:1205.3478v1 (cond-mat.stat-mech) 15 May (2012)
- ↑ Marc Meléndez, Wm. G. Hoover, and Pep Español "Comment on “Logarithmic Oscillators: Ideal Hamiltonian Thermostats”", Physical Review Letters 110 028901 (2013)
- ↑ Michele Campisi, Fei Zhan, Peter Talkner, and Peter Hänggi "Campisi et al. Reply", Physical Review Letters 110 028902 (2013)
- ↑ Daniel Sponseller and Estela Blaisten-Barojas "Failure of logarithmic oscillators to serve as a thermostat for small atomic clusters", Physical Review E 89 021301(R) (2014)
- Related reading