Clausius equation of state: Difference between revisions

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where
where


:<math>a = v_c - \frac{RT_c}{4P_c}</math>
:<math>a = \frac{27R^2T_c^2}{64P_c}</math>


:<math>b= \frac{3RT_c}{8P_c}-v_c</math>
:<math>b= v_c - \frac{RT_c}{4P_c}</math>


and
and


:<math>c= \frac{27R^2T_c^2}{64P_c}</math>
:<math>c= \frac{3RT_c}{8P_c}-v_c</math>


where <math>p</math> is the [[pressure]], <math>T</math> is the [[temperature]] and <math>R</math> is the [[molar gas constant]]. <math>T_c</math> is the [[critical points | critical]] temperature and <math>P_c</math> is the [[pressure]] at the critical point.
where <math>p</math> is the [[pressure]], <math>T</math> is the [[temperature]] and <math>R</math> is the [[molar gas constant]]. <math>T_c</math> is the [[critical points | critical]] temperature and <math>P_c</math> is the [[pressure]] at the critical point.

Revision as of 10:17, 14 October 2009

The Clausius equation of state is given by

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \left[p+{\frac {a}{T(v+c)^{2}}}\right](v-b)=RT}

where

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle a={\frac {27R^{2}T_{c}^{2}}{64P_{c}}}}
Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle b=v_{c}-{\frac {RT_{c}}{4P_{c}}}}

and

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle c={\frac {3RT_{c}}{8P_{c}}}-v_{c}}

where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle p} is the pressure, Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T} is the temperature and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle R} is the molar gas constant. Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle T_c} is the critical temperature and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle P_c} is the pressure at the critical point.

References

  1. R. Clausius "Ueber das Verhalten der Kohlensäure in Bezug auf Druck, Volumen und Temperatur", Annalen der Physik und Chemie 9 pp. 337-357 (1880)