Wohl equation of state

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The Wohl equation of state is given by[1] \[\left[ p + \frac{a}{Tv(v-b)} - \frac{c}{T^2v^3} \right] (v-b) = RT\]

where (Eq. 10 in [2]):

\[\left. a \right.= 6P_cT_cv_c^2\]

\[b= \frac{v_c}{4}\]

and

\[\left. c \right. = 4P_cT_c^2v_c^3\]

where \(p\) is the pressure, \(T\) is the temperature and \(R\) is the molar gas constant. \(T_c\) is the critical temperature and \(P_c\) is the pressure at the critical point.

[edit] References

  1. A. Wohl "Investigation of the condition equation", Zeitschrift für Physikalische Chemie (Leipzig) 87 pp. 1-39 (1914)
  2. K. K. Shah and G. Thodos "A Comparison of Equations of State", Industrial & Engineering Chemistry 57 pp. 30-37 (1965)
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