Pair stress approximation

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Pair stress approximation [1] for hard particles is given by (Eq. 3.18)

\[\rho B_2 = \frac{q}{(1+q)^{B_3}}\]

where \(q= P/k_BT\rho -1\), \(B_2\) is the second virial coefficient and \(B_3\) is the third virial coefficient.

[edit] See also

[edit] References

  1. Emmanuel Meeron and Arnold J. F. Siegert "Statistical Mechanics of Hard‐Particle Systems", Journal of Chemical Physics 48 pp. 3139-3155 (1968)
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