Thermodynamic integration
Thermodynamic integration is used to calculate the difference in the Helmholtz energy function between two states. The path must be continuous and reversible. One has a continuously variable energy function such that , and , Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle U_{\lambda }=U}
- Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \Delta A=A-A_{0}=\int _{0}^{1}d\lambda \langle {\frac {\partial U_{\lambda }}{\partial \lambda }}\rangle _{\lambda }}
where
- Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \left.U_{\lambda }\right.=(1-\lambda )U_{0}+\lambda U} .