Liu hard disk equation of state

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The Liu equation of state for hard disks (2-dimensional hard spheres) is given by Eq. 1, 9 and 13 of [1].

For the stable fluid:

Zv=1+η2/8+η4/18−4η4/21(1−η)2

where the packing fraction is given by η=πρσ2/4 where σ is the diameter of the disks.

The EoS for the stable fluid, liquid-hexatic transition region and hexatic:

Zlh=Zv+b1ηm1+b2ηm2(1−cη)

The global EoS for all phases:

Z=Zlh, η<=0.72

Z=Zsolid, η>0.72

where: Zsolid=2α+1.9+α−5.2α2+114.48α4

and α=231/2ρσ2


b1 −1.04191*108
b2 2.66813*108
m1 53
m2 56
Failed to parse (syntax error): {\displaystyle \frac{1}{c) } 0.75

References