Gibbs energy function
Definition:
where p is the pressure, V is the volume, and A is the Helmholtz energy function, i.e.
Taking the total derivative
From the Second law of thermodynamics one obtains
thus one arrives at
- Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \left.dG\right.=-SdT+Vdp}
For G(T,p) we have the following total differential
- Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle dG=\left({\frac {\partial G}{\partial T}}\right)_{p}dT+\left({\frac {\partial G}{\partial p}}\right)_{T}dp}