Hard sphere model

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Interaction Potential

The hard sphere interaction potential is given by


where Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle V\left(r \right) } is the potential energy between two spheres at a distance Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle r } , and Failed to parse (SVG (MathML can be enabled via browser plugin): Invalid response ("Math extension cannot connect to Restbase.") from server "https://wikimedia.org/api/rest_v1/":): {\displaystyle \sigma } is the sphere diameter.

Equations of state

Hard sphere fluid equations of state;

  1. See Carnahan-Starling (three dimensions)

Related systems

Hard disks in a 2-dimensional space

Hard rods in one dimension

Widom-Rowlinson model

Polydisperse hard spheres

Data

Virial coefficients of hard spheres and hard disks

References