Triangular well model

The triangular well model is given by

${\mathrm{\Phi }}_{12}(r)=\{\begin{array}{ccc}\mathrm{\infty }& ;& r\le \sigma \\ & ;& \sigma <r\le \lambda \sigma \\ 0& ;& r>\lambda \sigma \end{array}$

where ${\mathrm{\Phi }}_{12}(r)$ is the intermolecular pair potential, $r$ is the distance $r:=|{\mathbf{r}}_1-{\mathbf{r}}_2|$, $\sigma$ is the hard diameter, $ϵ$ is the well depth and λ > 1.

Equation of state

Main article: Equations of state for the triangular well model

References

1. Damon N. Card and John Walkley "Monte Carlo and Perturbation Calculations for a Triangular Well Fluid", Canadian Journal of Physics 52 pp. 80-88 (1974)
2. J. Largo and J. R. Solana "A simplified perturbation theory for equilibrium properties of triangular-well fluids", Physica A 284 pp. 68-78 (2000)
3. F. F. Betancourt-Cárdenas, L. A. Galicia-Luna and S. I. Sandler "Thermodynamic properties for the triangular-well fluid", Molecular Physics 105 pp. 2987-2998 (2007)
4. F. F. Betancourt-Cárdenas, L. A. Galicia-Luna, A. L. Benavides, J. A. Ramírez and E. Schöll-Paschinger "Thermodynamics of a long-range triangle-well fluid", Molecular Physics 106 pp. 113-126 (2008)