RSOZ for polydisperse systems

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For a polydisperse fluid, composed of nf components, in a polydisperse matrix, composed of nm components, written in matrix form in Fourier space (see Eq. 18 of Ref. 1):

H~mm=C~mm+ρmC~mmH~mm


H~fm=C~fm+ρmC~mmH~fm+ρfC~fmH~ff−ρfC~12H~fm


H~ff=C~ff+ρmC~fmTH~fm+ρfC~ffH~ff−ρfC~12H~12


H~12=C~12+ρmC~fmTH~fm+ρfC~ffH~12+ρfC~12H~ff−2ρfC~12H~12


Note: cfm=cmfT and hfm=hmfT.

(PD. I am not sure about the equation H~fm )

References

  1. S. Jorge; Elisabeth Schöll-Paschinger; Gerhard Kahl; María-José Fernaud "Structure and thermodynamic properties of a polydisperse fluid in contact with a polydisperse matrix", Molecular Physics 101 pp. 1733-1740 (2003)