Gibbs energy function: Difference between revisions

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:<math>dG=\left(\frac{\partial G}{\partial T}\right)_p dT + \left(\frac{\partial G}{\partial p}\right)_T dp</math>
:<math>dG=\left(\frac{\partial G}{\partial T}\right)_p dT + \left(\frac{\partial G}{\partial p}\right)_T dp</math>
[[Category: Classical thermodynamics]]

Revision as of 18:30, 23 February 2007

Definition:

Taking the total derivative

From the Second law of thermodynamics one obtains

thus one arrives at

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle \left.dG\right.=-SdT+Vdp}

For G(T,p) we have the following total differential

Failed to parse (Conversion error. Server ("https://wikimedia.org/api/rest_") reported: "Cannot get mml. Server problem."): {\displaystyle dG=\left({\frac {\partial G}{\partial T}}\right)_{p}dT+\left({\frac {\partial G}{\partial p}}\right)_{T}dp}