Enthalpy: Difference between revisions

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:<math>\left.H\right.=U+pV</math>
:<math>\left.H\right.=U+pV</math>


''(-pV)'' is a ''conjugate pair''. The differential of this function is
where <math>U</math>  is the [[internal energy]], <math>p</math> is the [[pressure]], <math>V</math> is the volume and ''(-pV)'' is a ''conjugate pair''. The differential of this function is


:<math>\left.dH\right.=dU+pdV+Vdp</math>
:<math>\left.dH\right.=dU+pdV+Vdp</math>

Revision as of 14:19, 29 January 2008

Definition of the enthalpy, H

H=U+pV

where U is the internal energy, p is the pressure, V is the volume and (-pV) is a conjugate pair. The differential of this function is

dH=dU+pdV+Vdp

From the Second law of thermodynamics one obtains

dH=TdS−pdV+pdV+Vdp

thus we arrive at

dH=TdS+Vdp

For H(S,p) we have the following total differential

dH=(∂H∂S)pdS+(∂H∂p)Sdp