Hard core Yukawa potential: Difference between revisions
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==Virial coefficients== | ==Virial coefficients== | ||
For the attractive form of the potential the [[Virial equation of state |virial coefficients]] have been calculated by Naresh and Singh <ref>[http://dx.doi.org/10.1016/j.fluid.2009.06.019 D.J. Naresh and Jayant K. Singh "Virial coefficients of hard-core attractive Yukawa fluids", Fluid Phase Equilibria '''285''' pp. 36-43 (2009)]</ref>. | For the attractive form of the potential the [[Virial equation of state |virial coefficients]] have been calculated by Naresh and Singh <ref>[http://dx.doi.org/10.1016/j.fluid.2009.06.019 D.J. Naresh and Jayant K. Singh "Virial coefficients of hard-core attractive Yukawa fluids", Fluid Phase Equilibria '''285''' pp. 36-43 (2009)]</ref>. | ||
==Liquid-vapour coexistence== | |||
<ref>[http://dx.doi.org/10.1063/1.3385894 E. B. El Mendoub, J.-F. Wax, and N. Jakse "Evolution of the liquid-vapor coexistence of the hard-core Yukawa fluid as a function of the interaction range", Journal of Chemical Physics '''132''' 164503 (2010)]</ref> | |||
==Phase diagram== | ==Phase diagram== | ||
:''Main article: [[Phase diagram of the Yukawa potential]]'' | :''Main article: [[Phase diagram of the Yukawa potential]]'' | ||
Revision as of 10:03, 23 April 2010
The hard core Yukawa potential has two forms, the attractive Yukawa potential:
![{\displaystyle \Phi _{12}\left(r\right)=\left\{{\begin{array}{lll}\infty &;&r<\sigma \\-\left({\frac {\epsilon \sigma }{r}}\right)\exp \left[-\kappa \left({\frac {r}{\sigma }}-1\right)\right]&;&r\geq \sigma \end{array}}\right.}](https://wikimedia.org/api/rest_v1/media/math/render/svg/54a0e1abaf83826da9b26ab63511f7429ad0fc77)
and the repulsive form
![{\displaystyle \Phi _{12}\left(r\right)=\left\{{\begin{array}{lll}\infty &;&r<\sigma \\\left({\frac {\epsilon \sigma }{r}}\right)\exp \left[-\kappa \left({\frac {r}{\sigma }}-1\right)\right]&;&r\geq \sigma \end{array}}\right.}](https://wikimedia.org/api/rest_v1/media/math/render/svg/bac4936e842e1c8959739f8910c4222cee4fc176)
where is the intermolecular pair potential, is the distance between site 1 and site 2, is the hard diameter, is the energy well depth (), and is a parameter that controls the interaction range ().
The repulsive form has been used to study charge-stabilised colloid-colloid interactions.
Critical point
For the attractive form of the potential, from a study of the law of corresponding states, one has (Eq. 3 in [1])
and (Eq. 4)
- .
The repulsive form of the potential has no critical point.
Triple points
The triple points for this model have been studied by Azhar and co-workers [2].
Virial coefficients
For the attractive form of the potential the virial coefficients have been calculated by Naresh and Singh [3].
Liquid-vapour coexistence
Phase diagram
- Main article: Phase diagram of the Yukawa potential
Two-term Yukawa potentials
Both the attractive and the repulsive form have been combined to produce the hard-sphere plus two Yukawa potential (H2Y) [5].
References
- ↑ Pedro Orea and Yurko Duda "On the corresponding states law of the Yukawa fluid", Journal of Chemical Physics 128 134508 (2008)
- ↑ Fouad El Azhar, Marc Baus, Jean-Paul Ryckaert and Evert Jan Meijer "Line of triple points for the hard-core Yukawa model: A computer simulation study", Journal of Chemical Physics 112 pp. 5121- (2000)
- ↑ D.J. Naresh and Jayant K. Singh "Virial coefficients of hard-core attractive Yukawa fluids", Fluid Phase Equilibria 285 pp. 36-43 (2009)
- ↑ E. B. El Mendoub, J.-F. Wax, and N. Jakse "Evolution of the liquid-vapor coexistence of the hard-core Yukawa fluid as a function of the interaction range", Journal of Chemical Physics 132 164503 (2010)
- ↑ Lloyd L. Lee, Michael C. Hara, Steven J. Simon, Franklin S. Ramos, Andrew J. Winkle, and Jean-Marc Bomont "Crystallization limits of the two-term Yukawa potentials based on the entropy criterion", Journal of Chemical Physics 132 074505 (2010)
Related reading
- J. Torres-Arenas, L. A. Cervantes, A. L. Benavides, G. A. Chapela, and F. del Río "Discrete perturbation theory for the hard-core attractive and repulsive Yukawa potentials", Journal of Chemical Physics 132 034501 (2010)
- Pedro Orea, Carlos Tapia-Medina, Davide Pini, and Albert Reiner "Thermodynamic properties of short-range attractive Yukawa fluid: Simulation and theory", Journal of Chemical Physics 132 114108 (2010)