Enthalpy: Difference between revisions
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Carl McBride (talk | contribs) m (New page: Definition: :<math>\left.H\right.=U+pV</math> ''(-pV)'' is a ''conjugate pair''. The differential of this function is :<math>\left.dH\right.=dU+pdV+Vdp</math> but from equation \ref{se...) |
Carl McBride (talk | contribs) mNo edit summary |
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:<math>\left.dH\right.=dU+pdV+Vdp</math> | :<math>\left.dH\right.=dU+pdV+Vdp</math> | ||
From the [[Second law of thermodynamics]] one obtains | |||
:<math>\left.dH\right.=TdS -pdV +pdV+Vdp</math> | :<math>\left.dH\right.=TdS -pdV +pdV+Vdp</math> |
Revision as of 18:04, 22 February 2007
Definition:
(-pV) is a conjugate pair. The differential of this function is
From the Second law of thermodynamics one obtains
thus we arrive at
For H(S,p) we have the following total differential