Wertheim's first order thermodynamic perturbation theory (TPT1): Difference between revisions
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:<math>Z_{\rm TPT1} = \frac{p}{\rho k_BT}= mZ_{\rm monomer}- (m-1)\left( 1 + \rho_{\rm monomer}\frac{\partial \ln {\rm g}(\sigma)}{\partial \rho_{\rm monomer}}\right)</math> | :<math>Z_{\rm TPT1} = \frac{p}{\rho k_BT}= mZ_{\rm monomer}- (m-1)\left( 1 + \rho_{\rm monomer}\frac{\partial \ln {\rm g}(\sigma)}{\partial \rho_{\rm monomer}}\right)</math> | ||
where <math>Z_{\rm monomer}</math> is the [[equations of state | equation of state]] of the monomer system and ''m'' is the number of monomers in the | |||
chains. | |||
==See also== | ==See also== | ||
*[[SAFT]] | *[[SAFT]] | ||
Revision as of 17:28, 13 July 2007
where is the equation of state of the monomer system and m is the number of monomers in the chains.
See also
References
- M. S. Wertheim "Fluids with highly directional attractive forces. I. Statistical thermodynamics" Journal of Statistical Physics 35 pp. 19-34 (1984)
- M. S. Wertheim "Fluids with highly directional attractive forces. II. Thermodynamic perturbation theory and integral equations" Journal of Statistical Physics 35 pp. 35-47 (1984)
- M. S. Wertheim "Fluids with highly directional attractive forces. III. Multiple attraction sites" Journal of Statistical Physics 42 pp. 459-476 (1986)
- M. S. Wertheim "Fluids with highly directional attractive forces. IV. Equilibrium polymerization" Journal of Statistical Physics 42 pp. 477-492 (1986)
- M. S. Wertheim "Thermodynamic perturbation theory of polymerization", Journal of Chemical Physics 87 pp. 7323-7331 (1987)