Glass transition: Difference between revisions

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In the laboratory the '''glass transition''' is not a sharp transition; its properties change smoothly across <math>T_g</math>.
*<math>T_g</math> ''increases'' with a decrease in the observation time, <math>\tau_{\rm obs}</math>.
*<math>\Delta H =0</math>
*<math>\Delta V =0</math>
==Ideal glass transition temperature==
==Ideal glass transition temperature==
See Ref 1.  
See Ref 1.  
==Observation time==
<math>\tau_{\rm obs}</math>
==Intrinsic average structural relaxation time==
==See also==
==See also==
*[[Kauzmann's paradox]]
*[[Kauzmann's paradox]]

Revision as of 14:16, 19 June 2007

In the laboratory the glass transition is not a sharp transition; its properties change smoothly across .

  • increases with a decrease in the observation time, .

Ideal glass transition temperature

See Ref 1.

Observation time

Intrinsic average structural relaxation time

See also

References

  1. C. A. Angell and J. C. Tucker "Heat capacities and fusion entropies of the tetrahydrates of calcium nitrate, cadmium nitrate, and magnesium acetate. Concordance of calorimetric and relaxational ideal glass transition temperatures", Journal of Physical Chemistry 78 pp. 278 - 281 (1974)
  2. Prabhat K. Gupta and John C. Mauro "The laboratory glass transition", Journal of Chemical Physics 126 224504 (2007)